Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 113, Issue 33, Pages 11384-11402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp903161j
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Funding
- DFG-NSF Materials World Network program [1674/4]
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Microphase separation of binary mixed A/B polymer brushes exposed to different solvents is studied using Single-Chain-in-Mean-Field simulations. Effects of solvent quality and selectivity, grafting density, composition, and chain-length asymmetry are systematically investigated, and diagrams of morphologies in various solvents are constructed as a function of grafting density and composition or chain-length asymmetry. The structure of the microphase segregated morphologies lacks long-range periodic order, and it is analyzed quantitatively Using Minkowski measures.
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