Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 113, Issue 42, Pages 13901-13909Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp906003m
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Funding
- Israel Science Foundation [494/05]
- U.S. Air Force [FA9550-06-1-0227]
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An electrolytical method is presented for the doping of metal with organic molecules (0.1-1% by weight). Several representative organic molecules, including dyes and polymers, have been entrapped in copper or silver using this procedure. The resulting doped metals have been characterized using TGA, UV-vis, SEM, EDS, and XRD. The dynamics of dye extraction from composites has been modeled, offering a means to quantify the leaching behavior of organics@metals. Typically, entrapped molecules are shown to be heterogeneously distributed within the composites, including a population which is entrapped tighter than with nonelectrolytic method.
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