Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 119, Issue 11, Pages 2225-2232Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp503999b
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Funding
- DFG (Deutsche Forschungsgemeinschaft) [Su 121/4]
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Infrared spectra Of isolated methanol acetone clusters up to tetramers are experimentally characterized for the flint time. They show evidence for a nanometer-scale demixing trend of the cold species. In combination with quantum calculations, the mutual repulsion is demonstrated to start beyond three molecular, units, whereas individual molecules still prefer to form a mixed complex.
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