Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 119, Issue 11, Pages 2543-2552Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp509006u
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Funding
- Deutsche Forschungsgemeinschaft
- DAAD (Deutscher Akademischer Austauschdienst)
- National Natural Science Foundation [21433005, 21173053]
- Ministry of Science and Technology of China [2013CB834603, 2012YQ220113-3]
- Committee of Science and Technology of Shanghai [13XD1400800]
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The novel neon complex NeBeCO3 has been prepared in a low-temperature neon matrix via codeposition of laser-evaporated beryllium atoms with O-2 + CO/Ne. Doping by the heavier noble gas atoms argon, krypton and xenon yielded the associated adducts NgBeCO(3) (Ng = Ar, Kr, Xe). The noble gas complexes have been identified via infrared spectroscopy. Quantum chemical calculations of NgBeCO(3) and NgBeO (Ng = He, Ne, Ar, Kr, Xe) using ab initio methods and density functional theory show that the Ng-BeCO3 bonds are slightly longer and weaker than the Ng-BeO bonds. The energy decomposition analysis of the Ng-Be bonds suggests that the attractive interactions come mainly from the Ng -> BeCO3 and Ng -> BeO sigma donation.
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