Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 115, Issue 24, Pages 6405-6412Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp108491a
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Funding
- CSIRO
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The kinetics of the interactions of aqueous ammonia with aqueous carbon dioxide/carbonate species has been investigated using stopped-flow techniques by monitoring the pH changes via indicators. The reactions include the reversible formation of ammonium carbamate/carbamic acid. A complete reaction mechanism has been established, and the temperature dependence of all rate and equilibrium constants including the protonation constant of the amine between 15 and 45 degrees C are reported and analyzed in terms of Arrhenius, Eyring, and van't Hoff relationships.
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