Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 114, Issue 48, Pages 12639-12645Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp107348h
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Funding
- National Science Foundation [CHE-0449598]
- Postgraduate Innovation Fund of Jiangsu Province [CX09B_141Z]
- Nanjing University of Technology [BSCX200812]
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The photophysical properties of a series of 4,6-diphenyl-2,2'-bipyridyl platinum(II) complexes bearing different sigma-alkynyl ancillary ligands (1a-1k) were systematically investigated. All complexes exhibit strong (1)pi,pi* absorption bands in the UV region; and broad, structureless charge-transfer band(s) in the visible region, which systematically red-shift(s) when the electron-donating ability of the para substituent on the phenylacetylide ligand increases. All complexes are emissive in solution at room temperature. When excited at the charge-transfer absorption band, the complexes exhibit long-lived orange emission (lambda(max): 555 601 nm), which is attributed to a triplet metal-to-ligand charge transfer/intraligand charge transfer emission ((MLCT)-M-3/(ILCT)-I-3). Most of these complexes exhibit broad triplet transient difference absorption in the visible to the near-IR region, with a lifetime comparable to those measured from the decay of the (MLCT)-M-3/(ILCT)-I-3 emission. The reverse saturable absorption (RSA) of these complexes were demonstrated at 532 nm using nanosecond laser pulses. The degree of RSA follows this trend: 1k approximate to 1a > 1c > 1f approximate to 1i > 1h approximate to 1b > 1e > 1d > 1g, which is mainly determined by the ratio of the triplet excited-state absorption cross section to that of the ground-state and the triplet excited-state quantum yield.
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