Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 114, Issue 12, Pages 4181-4187Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp1001622
Keywords
-
Funding
- Academy of Finland
- INTAS [05-1000008-8017]
- Faculty of Science of the University of Helsinki [7500101]
Ask authors/readers for more resources
We report three new noble-gas molecules prepared in low-temperature Kr and Xe matrices from the HCCF precursor by UV photolysis and thermal annealing. The identified molecules are two noble-gas hydrides HNgCCF (Ng = Kr and Xe) and a molecule of another type, HCCKrF. These molecules are assigned with the help of ab initio calculations. All strong absorptions predicted by theory are found in experiments with proper deuteration shifts. The experiments and theory suggest a higher stability against dissociation of HNgCCF molecules compared to HNgCCH reported previously. Surprisingly, only very tentative traces of HCCXeF, which is computationally very stable, are found in experiments. No strong evidence of similar argon compounds is found here.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available