Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 113, Issue 12, Pages 2796-2800Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp8109918
Keywords
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Funding
- U.S. Department of Energy
- Office of Basic Energy Sciences [DE FG03 01ER15237]
- DOE [DE-AC05-00OR22725.]
- DOE-BES [DE-AC02-06CH11357]
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The vibrational density of states (VDOS) for water confined on the surface of rutile-TiO2 nanoparticles has been extracted from low temperature inelastic neutron scattering spectra. Two rutile-TiO2 nanoparticle samples that differ in their respective levels of hydration, namely TiO2 center dot 0.37H(2)O (1) and TiO2 center dot 0.22H(2)O (2) have been studied. The temperature dependency of the heat capacities for the two samples has been quantified from the VDOS. The results from this study are compared with previously reported data for water confined on anatase-TiO2 nanoparticles.
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