Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 113, Issue 1, Pages 146-156Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp807840g
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The BrO3--SO32--Fe(CN)(6)(4-) (BSF) pH-oscillatory system is coupled to the Al(OH)(3) precipitation equilibrium (BSFA system) and studied in a stirred flow reactor. The dynamic behavior of the BSFA system differs significantly from that of the BSF system. In addition to the large-amplitude pH oscillations found in the BSF system, new small-amplitude and mixed-mode oscillations occur. A detailed mechanism of the BSFA system is developed and investigated.
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