Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 276, Issue -, Pages 104-112Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2013.11.018
Keywords
Quantum dots; Free base porphyrins; Metalloporphyrins; Electron transfer; Transient absorption measurements; Photoluminescence quenching
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Funding
- DST [SR/SI /PC-12/2011, 039680/E15/2011, 07722/E15/2012]
- UGC-BSR (RFSMS)
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Free base porphyrins and metalloporphyrins with different number of methoxy groups were synthesized to investigate the consequence of methoxy groups in the porphyrins on interaction with quantum dots through steady state, time resolved and transient absorption measurements. Spectral changes in the absorption and photoluminescence of quantum dots in the presence of porphyrins elucidate the binding affinity between them. From the photoluminescence quenching analysis, higher number of methoxy substituted zinc porphyrin was found to possess better binding affinity with quantum dots than the other porphyrins which divulges the role of methoxy substituents. The calculated reduction potential of the synthesized porphyrins was feasible for accepting electrons from the photoexcited quantum dots. Electron transfer mechanism is suggested based on energy level diagram, Rehm-Weller equation and transient absorption measurements. (C) 2013 Elsevier B.V. All rights reserved.
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