A highly sensitive and selective ratiometric fluorescent probe based on conjugated donor-acceptor-donor constitution of 1,8-naphthyridine for Hg2+

A new 1,8-naphthyridine based di-olefinic chemosensor was designed, synthesized and its sensing behavior towards metal ions was investigated by UV-vis, fluorescence and H-1 NMR spectroscopic methods. A highly Hg2+-selective fluorescence enhancing property (>1.5-fold) in conjunction with a visible colorimetric change from yellow to purple has been observed, leading to a potential fabrication of both naked-eye and fluorescence detection of Hg2+. Our designed sensor of the donor-acceptor-donor system shows high selectivity towards mercury(II) ion over other competing metal ions. (C) 2011 Elsevier B.V. All rights reserved.