Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 207, Issue 1, Pages 94-101Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2008.11.006
Keywords
Luminescence; Platinum(II) complexes; Palladium(II) complexes; Metal alkynyls; Carbazole
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Funding
- University of Hong Kong Foundation for Educational Development and Research Limited, and Strategic Research Theme on Molecular Materials [HKU 2/05C]
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A series of luminescent carbazole-containing palladium(II) and platinum(II) alkynyl complexes has been successfully synthesized and characterized. Through a systematic comparison study, the emission of the platinum(II) bis-alkynyl complexes has been assigned to originate from an admixture of (IL)-I-3/(3) MLCT excited states with predominantly IL character. (C) 2008 Elsevier B.V. All rights reserved.
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