4.5 Article

The Pressure-Temperature Path and the Origin of Phlogopite in Spinel-Garnet Peridotites from the Blansky Les Massif of the Moldanubian Zone, Czech Republic

Journal

JOURNAL OF PETROLOGY
Volume 50, Issue 10, Pages 1795-1827

Publisher

OXFORD UNIV PRESS
DOI: 10.1093/petrology/egp052

Keywords

garnet; metasomatism; peridotite; phlogopite; P-T conditions

Funding

  1. Japan Society of Promotion of Science [14403013, 17204047, M100130904, AVOZ 30130516]
  2. Society KN
  3. Grants-in-Aid for Scientific Research [14403013, 17204047] Funding Source: KAKEN

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A new lithotype of peridotite, phlogopite- and apatite-bearing spinel-garnet peridotite, associated with leucocratic granulite, has been recognized at the Plesovice quarry in the Gfohl Unit within the Moldanubian Zone of the Bohemian Massif Czech Republic. There are three equilibrium stages in the Plesovice peridotite. The existence of Stage. the precursor spinet +/-garnet peridotite stage, is supported by the presence of an aluminous (Al2O3 similar to 3.0 wt %) orthopyroxene megacryst in the matrix. The minimum temperature of Stage I was estimated to be 1020 +/- 15 degrees C Stage II is defined by the cores of relatively large (<3 mm long) grains of olivine, low-Al orthopyroxene (Al2O3 similar to 1.3-1.7 wt %), clinopyroxene, and chromian spinel [Cr/(Cr + Al) = 0.50-0.57], along with relatively small (<1 mm long) Ba-rich phlogopite (BaO = 1.0-4.0 wt %), Sr-rich apatite (SrO similar to 1.7 wt %) and rare potassic (K2O similar to 0.9-1.2 wt %) amphibole. Garnet generally occurs as large spheroidal grains (up to 20 mm in diameter). It contains inclusions of olivine, orthopyroxene, chromian spinel, and phlogopite, all of which have similar compositions to their matrix counterparts. Therefore, garnet appears to be in equilibrium with the matrix phases at Stage II. Application of appropriate geothermobarometers to the assemblage at Stage II yielded temperatures of 850-1030 degrees C and pressures of 2.3-3.5 GPa. Stage III is defined by aluminous orthopyroxene (Al2O3 similar to 2.1-4.0 wt %), aluminous clinopyroxene and aluminous spinel along with pargasitic amphibole and Ba-rich phlogopite in kelyphite: temperature conditions at this stage were estimated to be 730-770 (+/-27)degrees C at 0.8-1.5 GPa. Multiphase solid inclusions, mainly composed of phlogopite, dolomite, apatite and calcite with minor amounts of chlorite and magnesiohornblende, are present only within large grains of chromian. spinet, which are surrounded by kelyphites. The idiomorphic outline of the multiphase solid inclusions suggests that frozen remnants of carbonatite melts or supercritical,fluids were trapped in the spinet. The mineral assemblage. in the multiphase solid inclusions suggests relatively low-P and low-T conditions (T<750 degrees C; P<1.6 GPa) for its crystallization. Furthermore, the timing of the crystallization of the multiphase solid inclusions appears to predate Stage H, as most multiphase solid inclusions are completely surrounded by the host chromian spinet. These data suggest that the Plesovice peridotite experienced cooling after Stage I and was then then transformed to spinel-garnet peridotite by subsequent subduclion. processes.

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