4.6 Article

X-ray diffraction of molybdenum under shock compression to 450 GPa

Journal

PHYSICAL REVIEW B
Volume 92, Issue 17, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.92.174114

Keywords

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Funding

  1. NNSA through the National Laser Users' Facility Program [DE-NA0000856, DE-NA0002154]
  2. Laboratory Directed Research and Development Program at LLNL [12-SI-007]
  3. U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]

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Molybdenum (Mo) is a body-centered-cubic (bcc) transition metal that has widespread technological applications. Although the bcc transition elements are used as test cases for understanding the behavior of metals under extreme conditions, the melting curves and phase transitions of these elements have been the subject of stark disagreements in recent years. Here we use x-ray diffraction to examine the phase stability and melting behavior of Mo under shock loading to 450 GPa. The bcc phase of Mo remains stable along the Hugoniot until 380 GPa. Our results do not support previous claims of a shallow melting curve for molybdenum.

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