Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 751, Issue -, Pages 25-32Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2013.07.016
Keywords
Transition metal catalyst; Epoxidation; Asymmetric epoxidation; Review
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Various polymers, fine chemicals, pharmaceuticals, food additives and flavor & fragrance compounds are based on epoxide intermediates. This historical perspective covers the landmarks of molecular transition metal catalysts for olefin epoxidation. The historic developments of Mo and V catalysts, methyltrioxorhenium and both Sharpless and Jacobsen asymmetric epoxidation are covered and an outlook on new upcoming systems is given. (C) 2013 Elsevier B. V. All rights reserved.
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