Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 765, Issue -, Pages 39-45Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2014.04.030
Keywords
Iridium complex; 2,4,5-Trifluorophenylpyridine; 1,3,4-Oxadiazole; Organic light emitting diode; Efficiency
Categories
Funding
- National Natural Science Foundation of China [21371093]
- Major State Basic Research Development Program [2011CB808704, 2013CB922101]
- Natural Science Foundation of Jiangsu Province [BK20130054]
Ask authors/readers for more resources
Using 2,4,5-trifluorophenylpyridine as a monoanionic cyclometalated ligand, 2-(5-phenyl-1,3,4-oxadiazol-2-yl)phenol, 2-(5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl)phenol and 2-(5-(4-trifluoro-methylphenyl)-1,3,4-oxadiazol-2-yl)phenol as ancillary ligands, three new heteroleptic iridium(III) complexes (Ir(F(3,4,6)ppy)(2)POP, Ir(F(3,4,6)ppy)(2)FPOP and Ir(F(3,4,6)ppy)(2)CF3POP) were developed. All complexes are green phosphors (lambda(max) = 503-521 nm) with photoluminescence quantum efficiency yields of 12-18% in CH2Cl2 solutions at room temperature, respectively. The organic light emitting diodes (OLEDs) with the structure of ITO/TAPC (1,1-bis(4-(di-p-tolylamino)phenyl)cyclohexane, 60 nm)/Ir(F(3,4,6)ppy)(2)POP (6, 8, 10 wt%): SimCP2 (bis(3,5-di(9H-carbazol-9-yl)phenyl)diphenylsilane, 30 nm)/TPBi (1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl, 90 nm)/LiF (1 nm)/Al (100 nm) showed good performances. Particularly, the device with 8 wt% doped concentration exhibited superior performances with a peak current efficiency (eta(c)) of 61.49 cd A(-1) and a peak power efficiency (eta(p)) of 46.03 lm W-1. Furthermore, the efficiency roll-off ratios from the peak current efficiency to that at the practical luminance of 100 cd m(-2) and from 100 cd m(-2) to the benchmark brightness of 1000 cd m(-2) in this device are low, which are helpful to keep high efficiency at relatively high current density and high luminance. (C) 2014 Elsevier B.V. All rights
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available