4.5 Article

Rhodium-catalyzed arylation of acylsilanes with sodium tetraarylborates

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 765, Issue -, Pages 64-67

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2014.05.005

Keywords

Acylsilane; Addition; Alcohol; Boron; Homogeneous catalysis; Rhodium

Funding

  1. Grants-in-Aid for Scientific Research [25410054] Funding Source: KAKEN

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Rhodium(I)-catalyzed arylation of benzoylsilanes with sodium tetraarylborates affords alpha-silyl benzhydrols, benzhydryl silyl ethers, benzhydrols, and diaryl ketones selectively depending on the catalyst, solvent, and temperature. (C) 2014 Elsevier B.V. All rights reserved.

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