Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 750, Issue -, Pages 13-16Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2013.10.051
Keywords
Pincer complexes; PC(sp3)P; Chiral; Dibenzobarrelene
Categories
Funding
- Israel Science Foundation
Ask authors/readers for more resources
The manuscript describes a straightforward synthetic route toward a new family of chiral nonracemic dibenzobarrelene-based pincer ligands. The target molecules have been synthesized via lithiation of the racemic 1-bromo-8-diphenylphosphinotriptycene (2) and subsequent quenching with diastereomerically pure (1R,2S,5R)-(-)-menthyl (S)-p-toluenesulfinate. The resulting mixture of diastereomers was resolved using conventional column chromatography. Hydrogenation of the diastereomerically pure compounds lead to the formation of enantiopure PCS ligands. (C) 2013 Elsevier B. V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available