4.5 Article

Palladium(II)-Schiff base complex supported on multi-walled carbon nanotubes: A heterogeneous and reusable catalyst in the Suzuki-Miyaura and copper-free Sonogashira-Hagihara reactions

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 743, Issue -, Pages 63-69

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2013.06.021

Keywords

Cross-coupling reactions; Palladium complex; Suzuki reaction; Sonogashira reaction; Multi-walled carbon nanotubes

Funding

  1. K.N. Toosi University of Technology Research Council
  2. Iranian National Science Foundation (INSF) [90006262]

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The air-moisture stable and recyclable palladium(II) Schiff base complex anchored to multi-walled carbon nanotubes (Pd-Schiff base@MWCNTs) behaves as a very efficient heterogeneous catalyst in the Suzuki-Miyaura coupling of arylboronic acids and aryl halides, and the Sonogashira-Hagihara reaction of aryl iodides and terminal alkynes in aqueous media to afford the corresponding C-C couplings in high yields. (C) 2013 Elsevier B.V. All rights reserved.

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