Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 730, Issue -, Pages 37-43Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2012.07.046
Keywords
Platinum(II)-NHC complexes; Cyclometalation; Electronic effects; DFT calculations
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A series of C-C*-cyclometalated platinum(II) trifluoromethyl-acetylacetonate complexes could be synthesized via a new synthetic route. They have been characterized by standard methods (NMR, EA) as well as three solid-state structures. Quantum chemical calculations on the HOMO and LUMO levels show significant differences to the previously reported acetylacetonate derivatives. The influence of the CF3-groups on the photophysical properties is studied in detail. (C) 2012 Elsevier B.V. All rights reserved.
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