Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 724, Issue -, Pages 51-56Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2012.10.001
Keywords
Catalysis; 1-Alkenes; Organomagnesiums; Tantalum complexes
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Funding
- Russian Foundation for Basis Research [10-03-00046]
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Tantalum-catalyzed reaction of organomagnesium compounds (OMCs), bearing normal alkyl radicals, with 1-alkenes to afford novel iso-alkylmagnesiums has been systematically studied for the first time. The probable mechanism of the reaction implying the intermediate formation of beta,beta'-dialkyl substituted tantalacyclopentanes is discussed. (C) 2012 Elsevier B. V. All rights reserved.
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