Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 703, Issue -, Pages 51-55Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.12.033
Keywords
beta-Lactams; Hybrids; Aminocarbonylation; Palladium; Alkenyl iodides
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Funding
- Hungarian Government
- European Union
- European Social Fund
- Hungarian National Science Foundation [OTKA NK71906]
- Croatian Ministry of Science, Education and Sports [098-0982915-2948]
- Hungarian National Office of Research and Technology [OMFB-01247/2009]
- [TAMOP-4.2.2/B-10/1-2010-0025]
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Steroid-beta-lactam and steroid-beta-lactam-ferrocene conjugates were synthesized via palladium-catalyzed carbonylation of steroidal 17-iodo-16-enes in the presence of 3-amino-azetidin-2-ones. beta-Lactam derivatives have been used for the first time as nucleophiles in the aminocarbonylation reaction. The products were obtained in good yields and were characterized by H-1 and C-13 NMR, IR and HRMS. (C) 2012 Elsevier B.V. All rights reserved.
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