Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 26, Pages 4173-4178Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.09.009
Keywords
Water-soluble complexes; Pd(II) and Pt(II) complexes; Monosulfonated triphenylphosphine complexes; Aromatic cyanation; Biphasic catalysis
Categories
Funding
- Dongguk University
Ask authors/readers for more resources
Reaction of (COD)MX2 (M = Pd, Pt; X = Cl, I; COD = 1,5-cyclooctadiene) and P(C6H5)(2)(C6H4-p-SO3K) afforded water-soluble complexes MX2{P(C6H5)(2)(C6H4-p-SO3K)}(2) (M = Pd; X = Cl (1), M = Pt; X = Cl (2), I(3)) in high yields. Complexes 1-3 were fully characterized by various spectroscopic methods (IR, H-1-, C-13{H-1}- and P-31{H-1}-NMR spectroscopy) and elemental analyses. For 1 and 3, a mixture of the cis- and trans-isomer was produced from the reaction. For 2, however, only the cis-isomer was obtained. The stereochemistry of 1-3 can be assigned by the chemical shifts and the (1)J(Pt-P) values in P-31{H-1}-NMR spectral data. The ratios of the cis/trans isomers of 1 and 3 obtained from reactions in a range of solvents with various dielectric constants resulted in a little variation. However, addition of aqueous potassium halide solution to a DMSO-d(6) solution of 1 and 3 considerably increased the ratio of the cis/trans, respectively, indicating a strong intramolecular interligand Coulombic repulsion between the ionic phosphine ligands is present. Catalytic cyanation of aromatic iodide with KCN/ZnCl2 in n-heptane/water biphasic system has been tested in the presence of 1-3 with base. (C) 2011 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available