Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 716, Issue -, Pages 6-10Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2012.05.017
Keywords
Alkynes; Ene reaction; Homogeneous catalysis; Ruthenium
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Funding
- University of Southern California
- Hydrocarbon Research Foundation
- National Science Foundation [CHE-1054910, DBI-0821671, CHE-0840366]
- USC Provost Fellowship
- USC College Doctoral Fellowship
- NIH [S10-RR25432]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1054910] Funding Source: National Science Foundation
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Ruthenium(III) chloride hydrate is a convenient catalyst for the addition of active methylene compounds to aryl alkynes. These reactions are rapid, operationally simple, and high yielding in cases. Most significantly, no precautions are required to exclude air or water from the reactions. All reagents are commercially available at reasonable prices, and the reactions can be conducted in disposable glassware with minimal solvent. (C) 2012 Elsevier B.V. All rights reserved.
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