Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 699, Issue -, Pages 92-95Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.11.007
Keywords
sp(3)-Metalated; Pincer complexes; Triptycene; Platinum
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Funding
- Israel Science Foundation
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We describe the synthesis, characterization and properties of the new electrophilic palladium and platinum complexes bearing electron-rich PC(sp(3))P pincer ligands. We found that Lewis acidity of the compounds is low due to the strong sigma-donation of the sp(3)-carbometalated ligand backbone. (C) 2011 Elsevier B.V. All rights reserved.
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