Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 406-418Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.10.017
Keywords
Aminotroponiminate; Aminotroponate; Hydroamination; N-Ligands; Zinc
Categories
Funding
- Cluster of Excellence Unifying Concepts in Catalysis
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
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This review deals with the synthesis of aminotroponiminate and aminotroponate zinc complexes. The main focus is on their application as catalysts for the intramolecular hydroamination, in which good activity, particularly high functional group tolerance and a relatively high stability towards moisture and air were observed. In addition, a heterogeneous zinc catalyst was reported in order to increase the stability and the recyclability of the catalytic system. (C) 2010 Elsevier B.V. All rights reserved.
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