Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 316-320Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.09.045
Keywords
Gold; Hydroamination; Catalysis; Allene; Pyrrolidine
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Funding
- NIH [GM-080422]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM080422] Funding Source: NIH RePORTER
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Enantioselective intramolecular hydroamination of N-allenyl ureas catalyzed by an enantiomerically enriched bis(gold) phosphine complex forms pyrrolidine derivatives in good yield with up to 93% ee. (C) 2010 Elsevier B.V. All rights reserved.
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