Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 188-194Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.08.045
Keywords
N-heterocyclic carbenes; Platinum; Hydrosilylation
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Funding
- Engineering and Physical Sciences Research Council (EPSRC)
- Cardiff Catalysis Institute
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The synthesis and characterisation of a series of new 6- and 7-membered NHC (N-heterocyclic carbene) complexes 7-12 of zero valent platinum dvtms (divinyltetramethyldisiloxane), [Pt(NHC)(dvtms)] are reported. A number of the complexes were investigated as catalyst precursors in the hydrosilylation of a range of unsaturated substrates, including alkynes, alkenes and a ketone with triethylsilane and bis (trimethylsiloxy) methylsilane (MD'M), at low catalyst loading (0.005 mol %); in general, the activity, and the selectivity for 1-functionalised product was found to be high. (C) 2010 Elsevier B.V. All rights reserved.
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