Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 130-140Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.08.043
Keywords
Organophosphorus compounds; Transition metal catalysts; Regio- and stereoselective addition; H-P(O) bonds; Carbon-carbon unsaturated bonds
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In this short review, we briefly summarize our studies on metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated compounds (alkynes, alkenes, allenes, dienes and related). These new reactions provide regio- and stereoselective ways for the preparation of a variety of organophosphorus compounds. Mechanistic aspects related to the catalytic processes are discussed. (C) 2010 Elsevier B.V. All rights reserved.
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