4.5 Article

FeCl3-catalyzed addition of nitrogen and 1,3-dicarbonyl nucleophiles to olefins

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 296-304

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.09.031

Keywords

Iron; Hydroamination; Atom economy

Funding

  1. CNRS

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A direct intermolecular addition of nitrogen and 1,3-dicarbonyl nucleophiles to stabilized double bonds (styrenes, 1,3-dienes, enol-ethers, sugars..) in the presence of green and inexpensive FeCl3 catalyst is described. (C) 2010 Elsevier B.V. All rights reserved.

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