Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 695, Issue 24, Pages 2618-2628Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.08.026
Keywords
Palladation; Orthometallation; Palladacycle; Pincer complex; C-P cross-coupling
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Funding
- Utrecht University
- Council for the Chemical Sciences of the Netherlands Organization for Scientific Research (CW-NWO)
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A mono-and a 1,3-bis-phosphite arene ligand based on 2,2'-biphenol have been synthesized in order to study the synthesis of the corresponding palladium(II) complexes starting from different Pd precursors. Novel bis-phosphite palladium complex 1 [PdCl2(L)(2)] (L = dibenzo[d, f][1,3,2] dioxaphosphepin, 6-phenoxy), C, P-chelate bonded monophosphite palladium complex 2 [Pd(kappa(2)-L)(mu-Cl)](2), and PCP-pincer palladium complex 3 have been prepared from these ligands in promising to excellent yields (50-95%). Additionally, complexes 1 and 3 have been characterized by X-ray crystal structure determinations. The application of 2,6-bis-phosphite pincer palladium(II) complex 3 in C-P cross-coupling between diphenylphosphine-borane and a wide range of various aryl iodides under very mild conditions is reported. Kinetic investigations indicate that 3 merely acts as a pre-catalyst and that Pd nanoparticles are the actual catalytically active species. (C) 2010 Elsevier B.V. All rights reserved.
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