Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 695, Issue 2, Pages 260-266Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.10.001
Keywords
trans-Spanning; Bidentate ligands; Carbonylation; Palladium
Categories
Funding
- Israel Science Foundation [866/06]
- German Israeli Science Foundation for Research and Development [894/05]
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The manuscript describes the use of a trans-chelated palladium complex derived from 1,8-bis-(4-(diphenylphosphino)phenyl)anthracene (1) and p-TolPdI(TMEDA) as a precatalyst in carbonylative Suzuki coupling and methoxycarbonylation of aryl iodides and bromides. The catalyst is active in 0.01-1 mol% loading and demonstrates highly selective transformations. The selectivity is attributed to the unique structural features of the trans-chelating ligands. (C) 2009 Elsevier B.V. All rights reserved.
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