Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 17, Pages 2681-2699Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.03.017
Keywords
Electrochemistry; Oxidation; Reduction; Catalysis; Hydrogen
Categories
Funding
- National Science Foundation [CHE 0527003]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0749530] Funding Source: National Science Foundation
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This article reviews published literature on the electrochemical reduction and oxidation of complexes containing the Fe2S2 core characteristic of the active site of [FeFe]-hydrogenases. Correlations between reduction and oxidation potentials and molecular structure are developed and presented. In cases where the complexes have been studied with regard to their ability to catalyze the reduction of acids to give dihydrogen, the overpotentials for such catalyzed reduction are presented and an attempt is made to estimate, at least qualitatively, the efficiency of such catalysis. (C) 2009 Elsevier B. V. All rights reserved.
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