Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 6, Pages 930-936Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.11.023
Keywords
Enantioselective catalysis; Artificial metalloenzyme; Biotin-avidin technology; Oxidation; Schiff base
Categories
Ask authors/readers for more resources
Incorporation of achiral biotinylated manganese-salen complexes into streptavidin yields artificial metalloenzymes for aqueous sulfoxidation using hydrogen peroxide. Four biotinylated salen ligands were synthesized and their manganese complexes were tested in combination with several streptavidin mutants, yielding moderate conversions (up to 56%) and low enantioselectivities (maximum of 13% ee) for the sulfoxidation of thioanisole. (C) 2008 Elsevier B. V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available