Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 16, Pages 2576-2580Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.03.050
Keywords
Bioinorganic chemistry; Electrochemistry; [FeFe] Hydrogenase; Organometallic complexes; Pyridine ligand
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Funding
- National Key Foundation of China [20633020]
- National Natural Science Foundation of China [20471061]
- Science & Technology Innovation Foundation for Young Scholar of Fujian Province [2007F3112]
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Diiron model complexes (mu-pdt)Fe-2(CO)(5)L with L = pyridine ligands, e.g. py (A), etpy (B), btpy (C), were synthesized as active site analogues of [FeFe] hydrogenase, and characterized by X-ray crystallography and electrochemistry. Pyridine-N ligation was found to be able to tune the redox properties of the diiron centers of model complexes. (C) 2009 Elsevier B.V. All rights reserved.
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