Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 12, Pages 1903-1906Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.01.028
Keywords
Silylative coupling; Ruthenium hydride complexes; Vinylsiloxanes
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Funding
- Ministry of Science and Higher Education (Poland)
- [PBZ-KBN 118/T09/17]
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Efficient silylative coupling of linear vinyl-substituted oligo- and polysiloxanes with styrene in the presence of [RuHCl(CO)(PPh3)(3)] (1) and particularly [RuHCl(CO)(PCy3)(2)] (2) combined with copper(I) chloride is described. Treatment of styrene, with terminal or side vinyl group at siloxane skeleton catalyzed by [RuHCl(CO)(PCy3)(2)]/CuCl results in the quantitative and selective formation of respective silylative coupling products. (C) 2009 Elsevier B.V. All rights reserved.
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