Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 13, Pages 2114-2121Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.02.019
Keywords
Chelating ligands; Diamino-diols; Palladium(II) complexes; Homogeneous catalysis; Suzuki-Miyaura cross-coupling reaction; X-ray structures
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Funding
- Department of Science and Technology (DST), New Delhi [SR/S1/IC-02/2007]
- CSIR
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Inexpensive air and moisture stable diamino-diol ligands [(2-OH-C10H6)CH2(mu-NC4H8N)CH2(C10H6-2OH)] (1) and [(5-(BuC6H3)-Bu-t-2-OH)CH2(mu-NC4H8N)CH2(5-(BuC6H3)-Bu-t-2-OH)] (2) were synthesized by reacting corresponding alcohols with formaldehyde and piperazine. Treatment of ligands 1 and 2 with Pd(OAc)(2) in 1:1 molar ratio afforded neutral palladium complexes [Pd{(OC10H6)CH2(mu-NC4H8N)CH2(C10H6O)}] (3) and [Pd{(5-(BuC6H3)-Bu-t-2-O)CH2(mu-NC4H8N)CH2(5-(BuC6H3)-Bu-t-2-O)}] (4) in good yield. The palladium complexes 3 and 4 are employed in Suzuki-Miyaura cross-coupling reactions between phenylboronic acid and several aryl chlorides or bromides. They are found to be competent homogeneous catalysts for a variety of substrates to afford the coupled products in good to excellent yields. The crystal structures of compounds 2 and 4 are also reported. (c) 2009 Elsevier B.V. All rights reserved.
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