Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 5, Pages 604-606Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.12.049
Keywords
Carbene ligands; Tridentate ligands; Vanadium; Manganese
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Vanadium (V) and manganese (III) metal complexes (2, [(tBu)(OCO)]V(=O)Cl; 3,[(tBu)(OCO)]Mn(acac)), which are supported by a tridentate bis-aryloxide-N-heterocyclic carbene ligand ([(tBu)(OCO)](2) =[eta(3)-O,C,O-{(3,5-di-tert-butyl-C6H2O)(2)N2C3H4}](2)) have been prepared and structurally characterized. Both complexes were efficiently synthesized in a straightforward and smooth manner involving the direct reaction of the imidazolinium proligand 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)imidazolinium chloride 1, easily accessible in a two-step synthesis with an overall good yield, with ((PrO)-Pr-i)(3)V=O and Mn(acac)(3), respectively. (C) 2008 Elsevier B.V. All rights reserved.
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