4.5 Article

Synthesis of a bis(phenoxyketimine) palladium(II) complex and its activity in the Suzuki-Miyaura reaction

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 18, Pages 3008-3011

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.04.044

Keywords

Palladium catalyst; Suzuki-Miyaura reaction; Unactivated aryl bromides; Phenoxyketimine

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The synthesis of a new charge-neutral, air- and moisture-stable fluorinated bis(phenoxyketimine) Pd(II) complex is presented. Its activity as a precatalyst in the Suzuki-Miyaura cross-coupling reaction of activated and unactivated bromides has been explored. (C) 2009 Elsevier B.V. All rights reserved.

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