Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 693, Issue 26, Pages 3939-3942Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.09.065
Keywords
Iridium; C-H bond cleavage; Ketone; Alkyne; Alkene
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Funding
- Waseda University
- Japan Society for the Promotion of Science
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Cationic Ir complex ([Ir(cod)(2)]BF4 + BINAP) catalyzed the addition of ortho-C-H bonds in aryl ketones to alkynes, which gave alkenylated products in good to high yield. Styrene derivatives were good substrates, and the enantioselective addition to norbornene was also described. (C) 2008 Elsevier B. V. All rights reserved.
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