Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 693, Issue 14, Pages 2438-2442Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.04.029
Keywords
rhodium catalyst; arylation; arylboron compounds; C-H activation; phenylazoles; azobenzene
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The rhodium-catalyzed direct ortho-arylation reactions of phenylazoles using arylboron reagents such as tetraarylborates were examined. Ethyl chloroacetate and potassium fluoride were found to effectively act as a hydrogen acceptor and a promoter, respectively, to afford selective formation of the corresponding mono- or diarylated products with good yields. In addition, azobenzene as well as 2-phenylpyridine also underwent the direct arylation under similar conditions. (C) 2008 Elsevier B.V. All rights reserved.
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