Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 693, Issue 26, Pages 3787-3790Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.09.039
Keywords
Vinylic sulfides; Vinylic selenides; Vinylic tellurides; Nickel catalysis
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Funding
- FAPERGS
- CAPES
- MCT/CNPq
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A general method for the synthesis of vinylic chalcogenides by nucleophilic and Ni-catalyzed vinylic substitution on vinylic halides by phenyl chalcogenolates is described. The reactions were regio and stereo-selective for the nickel catalyzed substitution, and mixture of isomers was observed for some examples in the thermal process in DMF. (C) 2008 Elsevier B.V. All rights reserved.
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