Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 693, Issue 21-22, Pages 3321-3323Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.08.015
Keywords
phosphite ligands; carboranes; allylic amination; palladium
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Funding
- RFBR [08-03-00416-a]
- INTAS [05-1000008-8064]
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A series of chiral diphosphite ligands bearing sterically congested carborane fragments have been prepared and applied in the Pd-catalyzed allylic amination of 1,3-diphenylallyl acetate with pyrrolidine and di-n-propylamine (up to 83% ee). (C) 2008 Elsevier B.V. All rights reserved.
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