Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 19, Pages 12007-12022Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01925
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Funding
- Fonds der Chemischen Industrie
- Evonik Foundation
- Polytechnische Gesellschaft Frankfurt
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A highly modular, diastereoselective one-pot-synthesis of 1,3-diamines with three contiguous stereogenic centers is reported. Our method provides a fast and efficient access to 1,2-anti-2,3-anti-1,3-diamines from three readily available building blocks. This Bi(OTf)(3)-catalyzed reaction is insensitive to air and moisture and can be performed on a multigram scale.
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