Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 12, Pages 5875-5879Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo500820q
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Funding
- DST, New Delhi [SR/S2/JCB-11/2008]
- CSIR
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The use of a new ZnO-supported palladium(0) nanoparticle catalyst for the cyanation of aryl halides using a relatively benign cyanide source, K-4[Fe(CN)(6)], is described. This catalyst has been applied for the efficient cyanation of a variety of functionalized aryl bromides and activated aryl chlorides. This process circumvents the need for an additive and a ligand for the reaction and offers the advantages of high product yields, low catalyst loading (0.2 mol % Pd), and recyclability of the catalyst.
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