Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 2, Pages 736-741Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402593w
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Funding
- DST [SR/S1/OC-70/2008]
- CSIR, New Delhi
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A direct route to the synthesis of biologically active ellipticine quinones, olivacine, and calothrbcin B is described. The prominent key steps involved are Friedel-Crafts hydroxyalkylation followed by oxidation and directed ortho-lithiation reactions of readily available indole-2-carboxylate esters with appropriately substituted pyridine and quinoline carboxaldehydes.
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