Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 5, Pages 1979-1988Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402618r
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Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Science Foundation of China [21272010, 21332002]
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A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arenes from nitroaniline derivatives is described. This transformation can be applied to the synthesis of a series of functionalized trimethylstannyl arylboronates. In addition, the chemoselective reaction of the Stille and Suzuki-Miyaura cross-coupling reactions is explored, and a series of m- and p-terphenyl derivatives have been synthesized by conducting consecutive one-pot Stille and Suzuki-Miyaura cross-coupling reactions.
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