Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 24, Pages 12010-12017Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo5018712
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Funding
- Major Basic Research Development Program [2011CB833300]
- National Natural Science Foundation of China [21372242, 21272251, 21032007]
- Chinese Academy of Sciences
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
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By consideration of the mechanism of Pd-catalyzed cyclopropanation and allylation, NHC-pyridine compounds were adopted as the ligand in Pd-catalyzed cyclopropanation of esters and monosubstituted allylic reagents. The corresponding cyclopropanes were afforded as major products in moderate to good yields with high cyclopropane/allylation selectivity.
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