Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 10, Pages 4727-4734Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo5005179
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Funding
- National Natural Science Foundation of China [81123004, 81325020, 81361120410]
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An efficient TEMPO-air/cat. TEMPO-O-2 oxidative protocol was developed to synthesize multisubstituted or fused tetracyclic benzimidazoles via a metal-free oxidative C-N coupling between the sp(3) C-H and free N-H of readily available N-1-benzyl/alkyl-1,2-phenylenediamines.
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