Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 7, Pages 2934-2943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4028598
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- Department of Science & Technology (DST), New Delhi
- IISER Bhopal
- CSIR, New Delhi
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An unprecedented dehydrative C C bond formation between unprotected anilines with benzyl alcohols is disclosed. Re2O7 catalyst (5 mol %) at elevated reaction temperature (80 degrees C) provided C-benzylanilines with high to excellent yields and with good chemoselectivities (over N-alkylation). A probable mechanism has been proposed based on mechanistic studies.
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